Synthesis of (-)-Probetaenone I: Structural Confirmation of Biosynthetic Precursor of Betaenone B

DOI: 10.1039/P19900001228

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1228 - 1229 (1990)

Update date:2022-07-29

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Authors:

Miki, Shokyo

Sato, Yoshihiro

Tabuchi, Hiroyasu

Oikawa, Hideaki

Ichihara, Akitami

Sakamura, Sadao

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Article abstract of DOI:10.1039/P19900001228

(-)-Probetaenone I (1) has been synthesized by an intramolecular Diels-Alder reaction and, thereby, its structure has been clearly confirmed; in the biosynthesis of betaenone B (2) the stereochemistry of the C-8 hydroxylation of (1) was proved to involve retention of configuration.

Full text of DOI:10.1039/P19900001228

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