Journal of the Chemical Society. Perkin transactions I p. 1228 - 1229 (1990)
Update date:2022-07-29
Topics:
Miki, Shokyo
Sato, Yoshihiro
Tabuchi, Hiroyasu
Oikawa, Hideaki
Ichihara, Akitami
Sakamura, Sadao
(-)-Probetaenone I (1) has been synthesized by an intramolecular Diels-Alder reaction and, thereby, its structure has been clearly confirmed; in the biosynthesis of betaenone B (2) the stereochemistry of the C-8 hydroxylation of (1) was proved to involve retention of configuration.
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