Synthesis of the Mixed-metal Clusters ; Reactions of > (R = Ph or Et) and Crystal Structure of 3-Au(PPh3)>>

DOI: 10.1039/DT9940003069

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Journal of the Chemical Society, Dalton Transactions p. 3069 - 3074 (1994)

Update date:2022-07-29

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Authors:

Adatia, Trushar

Curtis, Hilary

Johnson, Brian F. G.

Lewis, Jack

McPartlin, Mary

Morris, Jill

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Article abstract of DOI:10.1039/DT9940003069

Treatment of the pentaruthenium salt 2 with an excess of (cod = cycloocta-1,5-diene) yielded the monoanion (1-) which has been isolated as its (1+) salt 1.Reaction of the monoanion with HBF4*Et2O gave the hydrido derivative 2.Compound 1 reacted with the gold salts Cl and Cl, respectively, to yield the cluster compounds > 3 and > 4.Compound 3 crystallises in the triclinic space group P<*> (no. 2) with a = 15.993(3), b = 9.728(2), c = 13.900(3) Angstroem, α = 90.29(2), β = 99.97(2), γ = 88.36(2) deg.The metal core geometry consists of a central Ru5Rh octahedron with one Ru3 face capped by a μ₃-Au(PPh3) fragment .The reactions of 3 and 4 with norbornadiene, PPh3 and P(OMe)3 are reported.

Full text of DOI:10.1039/DT9940003069

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