Chemistry - A European Journal p. 4737 - 4741 (2011)
Update date:2022-07-29
Topics:
Ye, Wenjing
Zhao, Miao
Du, Wangming
Jiang, Quanbin
Wu, Kaikai
Wu, Ping
Yu, Zhengkun
Exceptionally active ruthenium(II) complexes without an ancillary N-H functionality, but bearing a (chiral) unsymmetrical pyridyl-benzimidazolyl-based NNN ligand, exhibited very high catalytic activity in the (asymmetric) transfer hydrogenation ((A)TH) of ketones. The corresponding Ru-H complex, which is presumably the catalytically active species, was successfully isolated and structurally characterized by X-ray crystallography. Copyright
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