Journal of Organic Chemistry p. 5923 - 5924 (1990)
Update date:2022-08-05
Topics:
Chatani, Naoto
Sano, Takahiro
Ohe, Kouichi
Kawasaki, Yoshikane
Murai, Shinji
In the presence of Co2(CO)8, the reaction of benzyl acetates with HSiMe3 and carbon monoxide under mild reaction conditions (25 deg C, 1 atm of CO) resulted in the incorporation of CO to give β-phenethyl alcohols.The reaction is applicable to naphthyl-, furanyl-, thiophenyl-, and even ferrocenyl methyl acetates.
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