Journal of the Chemical Society, Dalton Transactions p. 2321 - 2324 (1990)
Update date:2022-08-04
Topics:
Deeming, Antony J.
Karim, Manzurul
Powell, Nicholas I.
The reaction of a = 30.738(9), b = 9.867(2), c = 16.048(9) Angstroem, β = 121.04(3) deg, and Z = 8, and the X-ray structure was refined to R = 0.0330 and R'= 0.0335.Molecules of (4) contain two chelating pyS ligands and the tungsten is seven-co-ordinated.Approximately determined exchange rates for the diastereotopic Me groups of PMe2Ph and of the non-equivalent pyS ligands are the same indicating that both exchanges result from the same process.The corresponding molybdenum compound is isostructural and shows similar fluxionality.
website:http://www.dulynet.com/
Contact:025-84699383 -8003
Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Guangxi Shanyun Biochemical Science and Technology Co., Ltd
Contact:+86-0772--6828887
Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
Contact:13120882795；+86-21-34621078;+86-021-31122318
Address:Suite 2,No.2715 Longwu Road
Tianjin Tensing Fine Chemical Research Develop Centre
Contact:86-022-23718576,13032267585
Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
Jintan City Mego Chemical Co., Ltd
Contact:+86-0519-82814387
Address:23# Dengguan Town, Jintan, Jiangsu Province, China
Doi:10.1142/S1088424620500236
(2020)Doi:10.1016/S0040-4039(00)97474-4
(1990)Doi:10.1016/S0040-4039(00)94489-7
(1990)Doi:10.1016/S0040-4020(01)87767-X
(1990)Doi:10.1016/S0040-4039(00)97686-X
(1990)Doi:10.1039/c1cc10210a
(2011)
