STEREOSELECTIVE REDUCTION OF ACYCLIC α-BROMO ESTERS

DOI: 10.1016/0040-4039(90)80163-G

Source and publish data:

Tetrahedron Letters p. 2845 - 2848 (1990)

Update date:2022-08-05

Topics:

Authors:

Guindon, Y.

Yoakim, C.

Lemieux, R.

Boisvert, L.

Delorme, D.

Lavallee, J.-F.

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Article abstract of DOI:10.1016/0040-4039(90)80163-G

Radical-based reduction of β-methoxy-or β-fluoro-α-bromo esters could be achieved with good stereoselection at low temperatures.A systematic evaluation of this reaction is presented and possible transition state models are discussed.

Full text of DOI:10.1016/0040-4039(90)80163-G

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