A NOVEL "Ti(0)" INDUCED ALLYLATION OF AMINES IN A TiCl4 (cat.)/ Al BIMETAL SYSTEM. CHIRALITY TRANSFER OF l-VALINE TO HOMOALLYLAMINE

DOI: 10.1016/S0040-4039(00)89015-2

Source and publish data:

Tetrahedron Letters p. 3023 - 3026 (1990)

Update date:2022-09-26

Topics:

Authors:

Tanaka, Hideo

Inoue, Keizo

Pokorski, Ulrike

Taniguchi, Masatoshi

Torii, Sigeru

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Article abstract of DOI:10.1016/S0040-4039(00)89015-2

"Barbier Type" allylation of imines with allyl bromide has been performed successfully by the action of aluminium (1 equiv.) and titanium(IV) chloride (0.05 equiv.) in THF.The chirality transfer of α-amino acid esters to homoallyl amines is demonstrated b

Full text of DOI:10.1016/S0040-4039(00)89015-2

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