Journal of Fluorine Chemistry p. 293 - 300 (1990)
Update date:2022-08-02
Topics:
Zhang, Yadong
Wen, Jianxun
Du, Wenying
Substitutions on <(pentafluorophenyl)ethynyl>trimethylsilylsilane (1) with nucleophiles, Nu-X (2) give the corresponding <(p-substituted-tetrafluorophenyl)ethynyl>trimethylsilanes (3) or (p-substituted-tetrafluorophenyl)ethynes (4).The trimethylsilyl group of (3) can be easily removed by treatment with dilute alkali to give <(p-substituted-tetrafluorophenyl)-ethynes (4).Diacetylenes containing fluoro-aromatic rings are prepared by the Chodkiewiez-Cadiot and the Hay coupling of the corresponding terminal acetylenes (4).
View MoreSuzhou Sibian Chemical Technology Co., Ltd
website:http://www.sibianpharm.com
Contact:+8618169181984,+8618013186906
Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
Shandong Xinke Petrochemical Co., Ltd.
Contact:+86-546-7277016
Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
Shenyang Xinyihan Chemical Technology Co., Ltd.
Contact:+86-18525026267
Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Zhejiang Sucon Silicone Co.,Ltd
Contact:+86-575-88046692
Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Shijiazhuang Frontierchem Co., Ltd.
Contact:+86-311-89271196
Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Doi:10.1139/v02-138
(2002)Doi:10.1021/ol060918g
(2006)Doi:10.1071/CH9901391
(1990)Doi:10.1055/s-2006-950304
(2006)Doi:10.1016/S0022-1139(00)80940-9
(1984)Doi:10.1039/jr9610003071
(1961)
