The invention of radical reactions. Part XXIX. Radical mono- and dideoxygenations with silanes

DOI: 10.1016/S0040-4020(01)80380-X

Source and publish data:

Tetrahedron p. 2793 - 2804 (1993)

Update date:2022-08-02

Topics:

Authors:

Barton Barton

Jang Jang

Jaszberenyi Cs.

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Article abstract of DOI:10.1016/S0040-4020(01)80380-X

Thionocarbonates and xanthates of primary and secondary alcohols, as well as bis-xanthates of vic-diols are readily deoxygenated to the corresponding hydrocarbons or olefins with phenylsilane, triphenylsilane, and triethylsilane in good yield.

Full text of DOI:10.1016/S0040-4020(01)80380-X

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