Tetrahedron Letters p. 3299 - 3300 (1990)
Update date:2022-07-29
Topics:
Griesbaum, Karl
Huh, Tae-Seong
Gutsche, Sven-Hendrik
Ozonolyses of 2-cyanopropene (1a) and of 2,4-dicyano-1-butene (1b) gave the corresponding ozonides 3-cyano-3-methyl- (2a) and 3-cyano-3-(2-cyanoethyl)-1,2,4-trioxolane (2b) as the first examples of their kind.Reduction with DMS yielded the expected fragments acetyl cyanide (4a) and β-cyanopropionyl cyanide (4b), along with formaldehyde.Reduction with triphenylphosphine, however, gave cyanomethyl acetate (6a) and cyanomethyl-β-cyanopropionate (6b), respectively.
View MoreJIN TAN CHENG'EN CHEMICAL CO.,LTD.
Contact:86-519-82116250
Address:NO.102，village Dongfang，conomic development zone
Contact:+86-10-83993285
Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Xinchang Yueding Chemical Co., Ltd.
Contact:86-571-56926323
Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd
Contact:+86-311-80817929
Address:Shangzhuang,Shijiazhuang,China
Onlychem (Jinan)Biotech Co.,Ltd
Contact:86-531-83175885
Address:No. 44, Honglou South Road, Jinan,China
Doi:10.1002/jhet.550
(2011)Doi:10.1016/j.tetlet.2016.10.087
(2016)Doi:10.1021/acs.joc.7b02178
(2017)Doi:10.1016/S0040-4020(01)89332-7
(1994)Doi:10.1016/S0040-4039(00)97689-5
(1990)Doi:10.1021/ja202954b
(2011)
