Synthesis of macrocycles via allylic radical intermediates. A total synthesis of (-)-zearalenone

DOI: 10.1016/S0040-4039(00)94465-4

Source and publish data:

Tetrahedron Letters p. 3641 - 3644 (1990)

Update date:2022-08-05

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Authors:

Hitchcock, Stephen A.

Pattenden, Gerald

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Article abstract of DOI:10.1016/S0040-4039(00)94465-4

A concise synthesis of optically active (-)-zearalenone (1) which uses a novel 14-endo trig macrocyclisation from an allylic radical intermediate (Scheme 1) as a key feature, is described.

Full text of DOI:10.1016/S0040-4039(00)94465-4

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