Chemistry Letters p. 2097 - 2100 (1987)
Update date:2022-08-04
Topics:
Matsuda, Fuyuhiko
Tomiyosi, Nobuya
Yanagiya, Mitsutoshi
Matsumoto, Takeshi
The C3-C17 segment of a boron containig ionophoric antibiotic aplasmomycin (1), the key intermediate in Corey's total synthesis of 1, was stereoselectively synthesized in an optically active form through remote controlled asymmetric reductions.
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