A Formal Synthesis of Aplasmomycin. Assembly of the C3-C17 Segment Based on Remote Controlled Asymmetric Reductions

DOI: 10.1246/cl.1987.2097

Source and publish data:

Chemistry Letters p. 2097 - 2100 (1987)

Update date:2022-08-04

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Authors:

Matsuda, Fuyuhiko

Tomiyosi, Nobuya

Yanagiya, Mitsutoshi

Matsumoto, Takeshi

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Article abstract of DOI:10.1246/cl.1987.2097

The C3-C17 segment of a boron containig ionophoric antibiotic aplasmomycin (1), the key intermediate in Corey's total synthesis of 1, was stereoselectively synthesized in an optically active form through remote controlled asymmetric reductions.

Full text of DOI:10.1246/cl.1987.2097

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