Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside

DOI: 10.1016/S0040-4039(00)97668-8

Source and publish data:

Tetrahedron Letters p. 4537 - 4538 (1990)

Update date:2022-08-04

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Authors:

Clausen, Thomas P.

Koller, John W.

Reichardt, Paul B.

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Article abstract of DOI:10.1016/S0040-4039(00)97668-8

Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates.

Full text of DOI:10.1016/S0040-4039(00)97668-8

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