Synthesis of 5-Deoxy-3-O-methyl-5-phenylphosphinyl-L-fucopyranoses. The first P-in-Ring Sugar Analogs of L-Fucose Type

Article abstract of DOI:10.1246/cl.1990.1359

Starting from 1,2:5:6-di-O-isopropylidene-β-D-altrofuranose, 5,6-dideoxy-1,2-O-isopropylidene-5-<(methoxy)phenylphosphinyl>-3-O-methyl-β-D-arabino-hexofuranose was prepared in a 6 step sequence (13percent overall yield).It was converted into the title com