Synthesis of racemic 6-deoxy-6-fluoro-chiro-inositol 2,3,5-trisphosphate

DOI: 10.1016/0008-6215(92)85049-6

Source and publish data:

Carbohydrate Research p. 207 - 215 (1992)

Update date:2022-09-26

Topics: Synthesis Chiral Enantiomers Racemic Experimental Phosphate

Authors:

Carless Carless

Busia Busia

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Article abstract of DOI:10.1016/0008-6215(92)85049-6

The synthesis of (±)-6-deoxy-6-fluoro-chiro-inositol 2,3,5-trisphosphate (4) is reported, starting from cyclohexa-1,4-diene. A key step involved the stereospecific 1,4-addition of singlet oxygen to trans-1,2-di-O-(2-methoxyethoxymethyl)cyclohexa-3,5-diene

Full text of DOI:10.1016/0008-6215(92)85049-6

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Product name:(1S,2R,3S,4S,5R,6S)-2,5-Bis-benzyloxy-3,4,6-tris-(2-methoxy-ethoxymethoxy)-cyclohexanol

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