Tetrahedron Letters p. 137 - 140 (1981)
Update date:2022-08-05
Topics:
Hayashi, Tamio
Kanehira, Koichi
Hioki, Tsuyoshi
Kumada, Makoto
Racemic Grignard reagents, 2-phenylpropylmagnesium chloride and 2-norbornylmagnesium chloride were kinetically resolved by asymmetric cross-coupling with vinyl bromides in the presence of chiral phosphine-nickel catalysts to give optically active coupling products (ca. 37percent ee) and carboxylic acids after carbonation with carbon dioxide.
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