Regioreversed Allylation in Lewis Acid-mediated and Photochemical Addition Reactions of Unsymmetric α-Diketones with Allylic Stannanes

DOI: 10.1246/cl.1990.1761

Source and publish data:

Chemistry Letters p. 1761 - 1764 (1990)

Update date:2022-09-26

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Authors:

Takuwa, Akio

Nishigaichi, Yutaka

Yamashita, Koichi

Iwamoto, Hidetoshi

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Article abstract of DOI:10.1246/cl.1990.1761

In the photochemical reaction of allyl- and benzyltrimethylstannanes with unsymmetric α-diketones (PhCOCOR), the allylic group was introduced to the benzoyl carbon in high or excellent selectivity, whereas the acyl carbon was allylated either exclusively

Full text of DOI:10.1246/cl.1990.1761

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