Regioreversed Allylation in Lewis Acid-mediated and Photochemical Addition Reactions of Unsymmetric α-Diketones with Allylic Stannanes

DOI: 10.1246/cl.1990.1761

Source and publish data:

Chemistry Letters p. 1761 - 1764 (1990)

Update date:2022-09-26

Topics:

Authors:

Takuwa, Akio

Nishigaichi, Yutaka

Yamashita, Koichi

Iwamoto, Hidetoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.1761

In the photochemical reaction of allyl- and benzyltrimethylstannanes with unsymmetric α-diketones (PhCOCOR), the allylic group was introduced to the benzoyl carbon in high or excellent selectivity, whereas the acyl carbon was allylated either exclusively

Full text of DOI:10.1246/cl.1990.1761

Products guided by the article

Product name:2-Ethyl-2-hydroxy-1-phenyl-pent-4-en-1-one

Cas No:130925-77-8

R&D Labs maybe for 130925-77-8

xujianqiang

Contact:86-21-57725962

Address:shanghai
Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
taicang liyuan chemical co,.ltd

website:http://www.tcliyuanchem.com/productse.php

Contact:86-512-53539583

Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China
Qingdao Pharmacypro Co., Ltd.

Contact:+86-532-55689660

Address:qingdao
Zhejiang Sucon Silicone Co.,Ltd

Contact:+86-575-88046692

Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.

Relevant to this article

A Convenient Synthesis of Rivaroxaban from (S)-Epichlorohydrin

Doi:10.1080/00304948.2020.1741300
(2020)
Efficient generation of ortho-naphthoquinone methides from 1,4-epoxy-1,4-dihydronaphthalenes and their annulation with allyl silanes

Doi:10.1002/anie.201207315
(2013)
Novel dual inhibitors of 5-lipoxygenase and thromboxane A₂ synthetase: Synthesis and structure-activity relationships of 3-pyridylmethyl-substituted 2-amino-6-hydroxybenzothiazole derivatives

Doi:10.1021/jm00045a011
(1994)
Chloroacetylenephosphonates in reactions with tetrazolethiones

Doi:10.1007/s11172-014-0497-7
(2014)
Chemical synthesis of biologically active monoglycosylated GM2-activator protein analogue using N-sulfanylethylanilide peptide

Doi:10.1002/anie.201303390
(2013)
Evaluation of net antioxidant activity of mono- and bis-Mannich base hydrochlorides and 3-keto-1,5-bisphosphonates from their ProAntidex parameter

Doi:10.1016/j.molstruc.2015.02.071
(2015)

Article Doi