Reaction of Benzeneseleninyl Chloride with Olefins in the Presence of a Lewis Acid. A Novel One Step Vinylic Chlorination

DOI: 10.1246/bcsj.61.449

Source and publish data:

Bulletin of the Chemical Society of Japan p. 449 - 454 (1988)

Update date:2022-08-03

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Authors:

Kamigata, Nobumasa

Satoh, Takeshi

Yoshida, Masato

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Article abstract of DOI:10.1246/bcsj.61.449

In the presence of aluminum chloride benzeneseleninyl chloride was found to be an exellent vinylic chlorinating reagent of olefins under mild conditions.However, such olefins as styrene, trans-stilbene, and trans-1-phenylpropene afforded dichloro adducts under similar conditions.A plausible reaction mechanism involving positive chlorine intermediate is proposed.

Full text of DOI:10.1246/bcsj.61.449

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