Bulletin of the Chemical Society of Japan p. 449 - 454 (1988)
Update date:2022-08-03
Topics:
Kamigata, Nobumasa
Satoh, Takeshi
Yoshida, Masato
In the presence of aluminum chloride benzeneseleninyl chloride was found to be an exellent vinylic chlorinating reagent of olefins under mild conditions.However, such olefins as styrene, trans-stilbene, and trans-1-phenylpropene afforded dichloro adducts under similar conditions.A plausible reaction mechanism involving positive chlorine intermediate is proposed.
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