REAGENT CONTROL IN THE ALDOL ADDITION OF CHIRAL BORON ENOLATES BASED ON THE 2,5-DIPHENYLBOROLANE LIGAND SYSTEM

DOI: 10.1016/S0040-4039(00)97489-6

Source and publish data:

Tetrahedron Letters p. 3863 - 3866 (1990)

Update date:2022-08-03

Topics:

Authors:

Reetz, M. T.

Rivadeneira, E.

Niemeyer, C.

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Article abstract of DOI:10.1016/S0040-4039(00)97489-6

Thioesters can be O-borylated using optically active chloro-2,5-diphenylborolane to produce chiral boron enolates which show complete reagent control in aldol additions to chiral α-amino aldehydes.

Full text of DOI:10.1016/S0040-4039(00)97489-6

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