Synthesis, structure, and reactivity of the first stable diaryllead(II) compound

DOI: 10.1021/om00047a014

Source and publish data:

Organometallics p. 25 - 26 (1991)

Update date:2022-07-30

Topics:

Authors:

Brooker, Sally

Buijink, Jan-Karel

Edelmann, Frank T.

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Article abstract of DOI:10.1021/om00047a014

Reaction of PbCl₂ with 2,4,6-(CF₃)₃C₆H₂Li results in the formation of the first stable diaryllead(II) compound, [2,4,6-(CF₃)₃C₆H₂]₂Pb (4). X-ray structural analysis shows that in the solid state 4 is a bent monomer. 4 reacts with 2,4,6-(CF₃)₃C₆H₂SH (5) in hydrocarbon solutions to produce the solvent-free thiolate [2,4,6-(C-F₃)₃C₆H₂S]₂Pb (6).

Full text of DOI:10.1021/om00047a014

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