Helvetica chimica acta p. 1373 - 1390 (1990)
Update date:2022-08-02
Topics: Nucleophilic addition
Drenkard
Ferris
Eschenmoser
2-Aminopropenenitrile in solvents such as MeCN, MeOH, or H2O is photoisomerized by UV light to racemic aziridine-2-carbonitrile (rac-2); the larger part of the starting material, however, fragments to HCN and MeCN. The observed photocyclization constitutes a structural connection within an ensemble of C3H4N2 compounds considered to be potentially relevant to prebiotic chemistry.
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Doi:10.1021/jo2006945
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