Studies on glycosides XIV. Stereoselectivity and reactivity of new C1 leaving group trichloroacetoxyl in glycosylation reaction

Article abstract of DOI:10.1080/00397919508011769

2,3,4,6-O-Tetrabenzyl-α-D-galactopyranosyl trichloroacetate (2) reacted with a series of nucleophiles in the presence of BF₃ · OEt₂ or TMSOTf to give O-, S-galactopyranosides and galactopyranosyl carboxylates stereoselectively in hig

Full text of DOI:10.1080/00397919508011769

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Studies on Glycosides XIV.
Stereoselectivity and Reactivity
of New C1 Leaving Group
Trichloroacetoxyl in Glycosylation
Reaction
Jianmin Mao a , Hongming Chen a , Jian Zhang a & Mengshen
Cai a
a Department of Organic Chemistry , School of
Pharmaceutical Sciences Beijing Medical University , Beijing,
100083, P. R. CHINA
Published online: 23 Sep 2006.
To cite this article: Jianmin Mao , Hongming Chen , Jian Zhang & Mengshen Cai (1995)
Studies on Glycosides XIV. Stereoselectivity and Reactivity of New C1 Leaving Group
Trichloroacetoxyl in Glycosylation Reaction, Synthetic Communications: An International
Journal for Rapid Communication of Synthetic Organic Chemistry, 25:10, 1563-1565, DOI:
10.1080/00397919508011769
To link to this article: http://dx.doi.org/10.1080/00397919508011769
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