Organic Letters p. 3368 - 3371 (2011)
Update date:2022-07-29
Topics:
Endo, Kohei
Ohkubo, Takahiro
Shibata, Takanori
The chemoselective Pd-catalyzed Suzuki-Miyaura cross-coupling reaction using a diborylmethane is reported. The use of an equimolar amount of base with a diborylmethane realized chemoselective coupling for the synthesis of various benzylboronate derivatives. Sterically hindered aryl bromides can give products in moderate to excellent yields.
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