Tetrahedron Asymmetry p. 575 - 579 (2011)
Update date:2022-08-05
Topics: Synthesis Palladium-Catalyzed Application Asymmetric Allylic Alkylation
Liu, Jibing
Chen, Guihua
Xing, Junwei
Liao, Jian
A class of novel chiral SO-S-type bidentate ligands based on the tert-butylsulfinyl moiety as the sole chiral source were designed and synthesized through a simple and efficient pathway. These ligands are effective catalyst precursors for the palladium-catalyzed allylic alkylation of 1,3-diphenyl-2-propenyl acetate and moderate to good stereoselectivities (up to 84% ee) were obtained.
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