Angewandte Chemie - International Edition p. 4983 - 4987 (2011)
Update date:2022-08-05
Topics: Column chromatography NMR spectroscopy Kinetic studies Enantioselectivity Steric hindrance Enantiomeric excess (ee) Asymmetric catalysis Oxidative Addition Reductive Elimination Electronic effects Substrate Scope Chiral HPLC Hydroacylation Unactivated Alkenes In Situ Monitoring Acyl group Turnover frequency (TOF) Catalytic conditions Turnover number (TON)
Piel, Isabel
Steinmetz, Marc
Hirano, Keiichi
Froehlich, Roland
Grimme, Stefan
Glorius, Frank
NHC-catalysis proto(n)type: The title reaction produces 21 different chroman-4-one-type products in good yields and excellent enantioselectivities, in each case building up a new all-carbon quaternary stereocenter (see scheme). Based on DFT calculations a
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Doi:10.1007/BF00487423
(1990)Doi:10.1016/0031-9422(90)87111-7
(1990)Doi:10.1021/ic200252z
(2011)Doi:10.1016/S0040-4039(00)97799-2
(1990)Doi:10.1002/adsc.201100592
(2012)Doi:10.1016/j.jorganchem.2011.04.008
(2011)
