Reactivity of Ruthenium 5,10,15,20-Tetramesitylporphyrin towards Diazoesters: Formation of Olefins

DOI: 10.1039/c39930000934

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 934 - 935 (1993)

Update date:2022-07-29

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Authors:

Collman, J. P.

Rose, E.

Venburg, G. D.

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Article abstract of DOI:10.1039/c39930000934

Ruthenium 5,10,15,20-tetramesitylporphyrin, Ru(tmp), reacts with 1 equiv. of N2CHCO2Et to afford the ethoxycarbonylcarbene in the presence of an excess of N2CHCO2Et; the latter catalyses the formation of diethyl maleate as the major product at a rate of approximately one turnover per second.

Full text of DOI:10.1039/c39930000934

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