Reactivity of Ruthenium 5,10,15,20-Tetramesitylporphyrin towards Diazoesters: Formation of Olefins

DOI: 10.1039/c39930000934

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 934 - 935 (1993)

Update date:2022-07-29

Topics:

Authors:

Collman, J. P.

Rose, E.

Venburg, G. D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930000934

Ruthenium 5,10,15,20-tetramesitylporphyrin, Ru(tmp), reacts with 1 equiv. of N2CHCO2Et to afford the ethoxycarbonylcarbene in the presence of an excess of N2CHCO2Et; the latter catalyses the formation of diethyl maleate as the major product at a rate of approximately one turnover per second.

Full text of DOI:10.1039/c39930000934

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ru(((CH₃)3C₆H₂)4C₂₀H₈N₄)(C₂H₄)

Cas No:131207-11-9

R&D Labs maybe for 131207-11-9

Sichuan Sangao Biochemical Co., Ltd

Contact:+86-28-84874233

Address:19F, Bldg.2, Shudu Center, Tianfu 2nd St., Hi-tech zone, Chengdu 610041, Sichuan Province, China.
Shanggao Ruiya Fine Chemicals Co., Ltd

Contact:+86-795-2592103

Address:Xingguang Nanlu,Shanggao County Industry Park
Aminodiscovery Co.,Ltd.

Contact:+86-535-8888888

Address:No.161 Haishi Rd.
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China

Relevant to this article

Dithiane induced cycloaddition/aromatization tactic for the synthesis of multisubstituted furans

Doi:10.1021/acs.orglett.6b00699
(2016)
Doi:10.1039/CT8895500306
(1889)
Synthesis and structure of heavier group 2 metal complexes with diselenoimidodiphosphinato ligand containing SreSe and BaeSe direct bonds

Doi:10.1016/j.jorganchem.2013.04.056
(2013)
Synthesis and in vitro cytotoxic evaluation of 7-chloro-4-anilino-quinoline amide derivatives

Doi:10.14233/ajchem.2013.14016
(2013)
Doi:10.1016/S0040-4020(01)99106-9
(1966)
An efficient synthesis of N,N-disubstituted 5-aminooxazoles

Doi:10.1055/s-1992-26270
(1992)

Article Doi