Stereospezifische Darstellung C-methylverzweigter Kohlenhydrate mit Tetramethylzirkonium(IV)

Article abstract of DOI:10.1016/0008-6215(90)80003-L

Branched glycals and glycosides containing an HO-C-CH3 group were obtained stereospecifically by the action of tetramethylzirconium(IV), upon either α,β-unsatured enuloses or pyranosiduloses.L-Olivomycal and the C-4 epimer of L-mycaral were obtained from