Synthesis of Doubly Bridgehead Substituted Bicyclopentanes. Radical Transformations of Bridgehead Halides and Carboxylic Acids

DOI: 10.1021/jo00001a058

Source and publish data:

Journal of Organic Chemistry p. 307 - 316 (1991)

Update date:2022-08-04

Topics:

Authors:

Kaszynski, Piotr

Murdie, Neil D. Mc

Michl, Josef

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00001a058

Synthetic transformations of the 1-bicyclo<1.1.1>pentyl bridgehead radicals 11 generated from the corresponding bridgehead iodides 3 and carboxilic acids 5 are described.The relatively high nucleophilicity of these radicals was utilized in reactions with

Full text of DOI:10.1021/jo00001a058

Products guided by the article

Product name:methyl 3-tert-butoxybicyclo<1.1.1>pentane-1-carboxylate

Cas No:131515-45-2

R&D Labs maybe for 131515-45-2

Sichuan Sangao Biochemical Co., Ltd

Contact:+86-28-84874233

Address:19F, Bldg.2, Shudu Center, Tianfu 2nd St., Hi-tech zone, Chengdu 610041, Sichuan Province, China.
Jiangsu Zenji Pharmaceuticals LTD

Contact:+86-025-83172562; +1-224-888-1133(USA)

Address:No.5 Xinmofan Road
Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu

Relevant to this article

Comprehensive and facile entry into substituted amidines via the condensation of N-Pmc-substituted thioamides with amines using mukaiyama reagent as a thiophile

Doi:10.1055/s-0030-1260011
(2011)
Synthesis, structural characterization, photophysical properties and theoretical analysis of gold(I) thiolate-phosphine complexes

Doi:10.1039/c1dt10437c
(2011)
Mesoporous poly(melamine-formaldehyde): A green and recyclable heterogeneous organocatalyst for the synthesis of benzoxazoles and benzothiazoles using dioxygen as oxidant

Doi:10.1002/cctc.201402628
(2014)
Preparation of perinones via a novel multicomponent synthesis of isoindole scaffold

Doi:10.1016/j.tet.2011.05.078
(2011)
Versatile synthesis of 4-spiro-β-lactam-3-carbonitriles via the intramolecular nucleophilic cyclization of N-(p-hydroxyphenyl)cyanoacetamides

Doi:10.1016/j.tet.2014.05.008
(2014)
III. Thioanalogs of sparteine lactams. (+)-17-Thionosparteine and its perchlorate salt

Doi:10.1515/znb-2002-0514
(2002)

Article Doi