Tetrahedron Letters p. 5603 - 5606 (1990)
Update date:2022-08-05
Topics:
Discordia, Robert P.
Murphy, Christopher K.
Dittmer, Donald C.
Racemic trans-secondary allylic alcohols can be converted to homochiral cis-secondary allylic alcohols by means of a telluride-mediated transposition reaction applied to the homochiral glycidol obtained from a Sharpless kinetic resolution. (+)-Linalool is obtained in>95% enantiomeric excess from geraniol, an example of a transposition of a primary allylic alcohol to a homochiral tertiary alcohol.
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