Palladium-catalyzed cyclizations of polyenynes. A palladium zipper

DOI: 10.1021/ja00074a008

Source and publish data:

Journal of the American Chemical Society p. 9421 - 9438 (1993)

Update date:2022-07-29

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Authors:

Trost, Barry M.

Shi, Yian

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Article abstract of DOI:10.1021/ja00074a008

The cycloisomerization of polyenynes with a catalyst derived from Pd(0), acetic acid, and a ligand to polycycles depends upon the juxtaposition of unsaturation. The process involves the stages of initiation (by addition of Pd-H to an acetylene), propagati

Full text of DOI:10.1021/ja00074a008

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