Journal of the Chemical Society. Perkin transactions II p. 1709 - 1714 (1990)
Update date:2022-07-29
Topics:
Yamaoka, Tsuguo
Adachi, Hiroshi
Matsumoto, Kazuo
Watanabe, Hiroo
Shirosaki, Tsutomu
While o-nitrobenzyl aromatic sulphonates are known to photodissociate via an intramolecular rearrangement, photodissociation of p-nitrobenzyl aromatic sulphonates has not been reported.In this study, we report that p-nitrobenzyl 9,10-dimethoxyanthracene-2-sulphonate is photochemically dissociated to give 9,10-dimethoxyanthracene-2-sulphonic acid, 9,10-dimethoxy-2-(p-nitrobenzyl)-anthracene, and p,p'-dinitrobibenzyl.The dissociation is considered to proceed via an intramolecular electron transfer from the 9,10-dimethoxyanthracene moiety to the p-nitrobenzyl moiety.The quantum yield of the photodissociation in acetonitrile is 0.11 and the spectral response extends to 450 nm.The quantum yield is much higher than those of o-nitrobenzyl esters.
View MoreNanjing Norris Pharm Technology Co., Ltd.
Contact:+86-13901585132
Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Sinoway International (Jiangsu) Co., Ltd.
Contact:+86-25-86630167
Address:17 Beijing Road (West), Nanjing, China
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
website:http://www.trustwe.com
Contact:+86-21-61551413
Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong
Anhui Xinyuan Technology Co.,Ltd
Contact:0086-559-3515800
Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Engineering Research Center of Pesticide, Heilongjiang Province
Contact:+86-451-86609001
Address:No.74 of Xuefu Road, Nangang District,
Doi:10.1007/s00044-010-9547-3
(2012)Doi:10.1007/BF00509704
(1990)Doi:10.1021/jo00941a030
(1973)Doi:10.1039/c4nj02319f
(2015)Doi:10.1016/j.mencom.2011.07.004
(2011)Doi:10.1248/cpb.45.327
(1997)
