Short and efficient syntheses of gabosine I, streptol, 7-O-acetylstreptol, 1-epi-streptol, gabosine K, and carba α-d-glucose from δ-d-gluconolactone

DOI: 10.1055/s-0030-1260547

Source and publish data:

Synlett p. 1318 - 1320 (2011)

Update date:2022-08-03

Topics:

Authors:

Shing, Tony K. M.

Chen Chen

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Article abstract of DOI:10.1055/s-0030-1260547

δ-d-Gluconolactone was carbocyclized into an EOM-protected cyclohexenone in four steps involving perethoxymethylation, phosphonate anion addition, reduction, and oxidation with concomitant Horner-Wadsworth-Emmons alkenation. The stable key enone was effic

Full text of DOI:10.1055/s-0030-1260547

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