Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2367 - 2370 (1990)
Update date:2022-08-02
Topics:
Balueva, A. S.
Nikonov, G. N.
Vul'fson, S. G.
Sarvarova, N. N.
Arbuzov, B. A.
1-Butyl-1-dibutylboryl-2-diethylphosphino-2-phenylethene reacts with chloral and oxygen in a manner similar to 1-butyl-1-dibutylboryl-2-diphenylphosphino-2-phenylethene but, unlike the former, can also react with carbon disulfide to form a cyclic complex through an intramolecular S -> B coordination bond; charge density transfer from sulfur to boron consisted of about 0.3 e.
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