A new method for the synthesis of [3]-cumulenes and eneynecumulenes related to neocarzinostatin chromophore

DOI: 10.1016/S0040-4039(00)88518-4

Source and publish data:

Tetrahedron Letters p. 7469 - 7472 (1990)

Update date:2022-08-02

Topics:

Authors:

Saito, Isao

Yamaguchi, Kazuhiro

Nagata, Ryu

Murahashi, Eiji

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Article abstract of DOI:10.1016/S0040-4039(00)88518-4

A convenient method for the synthesis of [3]-cumulenes based on a Horner-Emmons type reaction of allenyldiphenylphosphine oxides with aldehydes or ketones has been described. A facile two-step synthesis of eneynecumulenes has been accomplished by this met

Full text of DOI:10.1016/S0040-4039(00)88518-4

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