Polar vs steric effects in the 1,3-dipolar cycloaddition reactions of acetonitrile oxide and 2-endo-acetoxy-5-halo-7-oxabicyclo[2.2.1]hept-5-en-2-exo-carbonitrile

DOI: 10.1016/S0040-4020(01)81474-5

Source and publish data:

Tetrahedron p. 8179 - 8186 (1990)

Update date:2022-08-04

Topics:

Authors:

Arjona Arjona

De Dios De Dios

Fernandez De La Pradilla

Mallo Mallo

Plumet Plumet

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)81474-5

The regioselectivity of the cycloaddition reactions between acetonitrile oxide and a number of 7-oxabicyclo[2.2.1]hept-5-enes is discussed. Acetonitrile oxide adds with complete regioselectivity to 2-endo-acetoxy-5-halo-7-oxabicyclo[2.2.1]hept-5-en-2-exo-

Full text of DOI:10.1016/S0040-4020(01)81474-5

Products guided by the article

Product name:Acetic acid (1S,2S,6R,7S,8S)-2-chloro-8-(3-methyl-[1,2,4]oxadiazol-5-yl)-5-(2,4,6-trimethyl-phenyl)-3,10-dioxa-4-aza-tricyclo[5.2.1.0^2,6]dec-4-en-8-yl ester

Cas No:132608-13-0

R&D Labs maybe for 132608-13-0

NEM CHEMICAL CO.，LTD

website:http://www.NEM.COM.CN

Contact:+86-393-4411771

Address:The west section of shengli Road,Puyang,Henan Province,China
Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Ji'an Kexin Trade Co., Ltd.(expird)

Contact:86-0796-8187704 18507063190

Address:ji'an jiangxi
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549

Relevant to this article

Synthesis, crystal structures, photophysical properties, and bioimaging of living cells of bis-β-diketonate phenothiazine ligands and its cyclic dinuclear complexes

Doi:10.1021/ic200150h
(2011)
2-Halobenzenesulfonyl chlorides in the synthesis of pyrido[2,1-c][1,2,4]benzothiadiazine 5,5-dioxide derivatives

Doi:10.1007/s11172-016-1518-5
(2016)
Cascade reaction of isatins with heterocyclic ketene aminals: Synthesis of imidazopyrroloquinoline derivatives

Doi:10.1021/ol201783d
(2011)
Pregnane glycosides from Hemidesmus indicus

Doi:10.1016/S0031-9422(00)86891-0
(1994)
Stereochemistry of novel triterpenes from Cynanchum hancokianum

Doi:10.1248/cpb.39.2271
(1991)
Doi:10.1021/jo01352a004
(1957)

Article Doi