Crystallographic Approach to the Origin of 'Syn-Effect'

DOI: 10.1246/cl.1990.2153

Source and publish data:

Chemistry Letters p. 2153 - 2156 (1990)

Update date:2022-08-05

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Authors:

Inomata, Katsuhiko

Hirata, Takaki

Sasada, Yoshihiro

Asada, Takahiro

Senda, Hitoshi

Kinoshita, Hideki

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Article abstract of DOI:10.1246/cl.1990.2153

It was revealed by X-ray crystallography that α-unsubstituted (E)-vinyl sulfones have syn-conformation which seems to be the cause of 'syn-effect' found in the conversion of (E)-vinyl sulfones to the corresponding allyl sulfones with a base under mild con

Full text of DOI:10.1246/cl.1990.2153

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