Intramolecular Hetero Diels-Alder Reaction of 1-Thiabutadienes, 1-Aryl-3-propene-1-thiones and 2--3,4-dihydronaphthalene-1(2H)-thiones

DOI: 10.1039/c39900001665

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1665 - 1667 (1990)

Update date:2022-09-26

Topics:

Authors:

Saito, Takao

Nagashima, Masumi

Karakasa, Takayuki

Motoki, Shinichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900001665

α,β-Unsaturated thioketones 4, 5 and 9, which are formed in situ by thionation of the corresponding ketones, undergo intramolecular hetero Diels-Alder reactions with high regio- and diastereo-selectivities (trans/cis) to give dihydrothiopyran-fused cycloadducts 6, 7 and 10.

Full text of DOI:10.1039/c39900001665

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(E)-3-(2-Allyloxy-phenyl)-1-p-tolyl-propenone

Cas No:132629-77-7

R&D Labs maybe for 132629-77-7

Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
ZIBO GREEN TRADE CO., LTD

Contact:0543-3317184

Address:No.1401, Unit 1, Global building, Binzhou city, shandong PRC.
Anhui Dexinjia Biopharm Co., Ltd

Contact:+86-531-82375818

Address:9 Hexie Road, kaifaqu, Taihe

Relevant to this article

Zirconium-catalyzed cycloalumination of alkenes in the one-pot synthesis of 3-substituted 1H-phospholane oxides

Doi:10.1016/j.mencom.2017.01.006
(2017)
Synthesis and Some Pharmacological Properties of Potent and Selective Antagonists of the Vasopressor (V₁-Receptor) Response to Arginine-Vasopressin

Doi:10.1021/jm00080a027
(1992)
Manganese(III)-mediated oxidative annulation of vinylidenecyclopropanes with 1,3-dicarbonyl compounds

Doi:10.1016/j.tet.2011.06.109
(2011)
Synthesis and biological evaluation of the glycoside (25R)-3β, 16β-diacetoxy-22-oxocholest-5-en-26-yl β-d-glucopyranoside: A selective anticancer agent in cervicouterine cell lines

Doi:10.1016/j.ejmech.2011.05.058
(2011)
Synthesis of cis and trans Bis-alkynyl complexes of Cr(III) and Rh(III) supported by a tetradentate macrocyclic amine: A spectroscopic investigation of the M(III)-alkynyl interaction

Doi:10.1021/ic2009336
(2011)
Dioxazoles, a new mild nitrene transfer reagent in gold catalysis: Highly efficient synthesis of functionalized oxazoles

Doi:10.1039/c6cc02776h
(2016)

Article Doi