Substrate Acidities and Conversion Times for Reactions of Amides With Di-tert-butyl Dicarbonate

DOI: 10.1016/0040-4039(95)01931-7

Source and publish data:

Tetrahedron Letters p. 8949 - 8952 (1995)

Update date:2022-08-03

Topics:

Authors:

Hansen, Marvin M.

Harkness, Allen R.

Coffey, D. Scott

Bordwell, Frederick G.

Zhao, Yongyu

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Article abstract of DOI:10.1016/0040-4039(95)01931-7

The conversion time for 4-dimethylaminopyridine catalyzed reaction of amides with tert-butyl dicarbonate varies dramatically with substrate acidity.The pK_a's in DMSO of some amides are determined to support correlation of reactivity with substr

Full text of DOI:10.1016/0040-4039(95)01931-7

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