1,5-Asymmetric induction in reactions between δ-alkoxyallylstannanes and aldehydes induced by tin (IV) chloride

DOI: 10.1016/S0040-4039(00)97034-5

Source and publish data:

Tetrahedron Letters p. 6239 - 6242 (1990)

Update date:2022-08-03

Topics:

Authors:

McNeill McNeill

Thomas Thomas

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Article abstract of DOI:10.1016/S0040-4039(00)97034-5

Treatment of (S)-4-benzyloxypent-(2E)-2-enyl(tributyl)stannane (3) with tin (IV) chloride at -78°C, followed by the addition of an aldehyde, gives 1,5-diol derivatives (6) with excellent 1,5-diastereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)97034-5

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