Mixed organofluorine - Organosilicon chemistry: Reaction of perfluoroorganometallic reagents with benzoylsilane

DOI: 10.1016/S0040-4039(00)71224-X

Source and publish data:

Tetrahedron Letters p. 83 - 86 (1991)

Update date:2022-08-05

Topics:

Authors:

Portella, Charles

Dondy, Boniface

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Article abstract of DOI:10.1016/S0040-4039(00)71224-X

Reaction of a perfluoroorganometallic (Mg or Li) reagent with benzoylsilanes gives, depending on the metal, the substituents and the reaction conditions, the F-alkyl phenyl trialkylsilyl carbinol 3, the F-alk-1-enyl phenyl ketone 4 or the 1-phenyl-1-trialkylsilyloxy-F-alk-1-ene 7.

Full text of DOI:10.1016/S0040-4039(00)71224-X

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