Carbohydrate-derived partners display remarkably high stereoselectivity in aldol coupling reactions

DOI: 10.1016/S0040-4020(01)80916-9

Source and publish data:

Tetrahedron p. 189 - 204 (1991)

Update date:2022-08-03

Topics:

Authors:

Kuo Long Yu

Handa Handa

Tsang Tsang

Fraser-Reid

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Article abstract of DOI:10.1016/S0040-4020(01)80916-9

Aldol condensation between 3-keto and aldehyde sugars have been studied. The enolate 3 reacts with aldehydes preferentially from the β-face to give axial C2 condensation products. However, if the reaction conditions are not controlled properly some C2 epi

Full text of DOI:10.1016/S0040-4020(01)80916-9

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