CATALYTIC ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS

DOI: 10.1016/S0040-4039(00)88562-7

Source and publish data:

Tetrahedron Letters p. 7345 - 7348 (1990)

Update date:2022-08-03

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Authors:

Irie, Ryo

Noda, Keiko

Ito, Yoshio

Matsumoto, Naohide

Katsuki, Tsutomu

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Article abstract of DOI:10.1016/S0040-4039(00)88562-7

Manganese complex of the optically active salen ligand -(1R,2R)-1,2-diphenylethylenediaminato> was found to be an effective catalyst for the enantioselective epoxidation of unfunctionalized olefins.The highest enantioselectivity of 50 percent ee was realized for (E)-1-phenyl-1-propene.

Full text of DOI:10.1016/S0040-4039(00)88562-7

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