Chemistry of Heterocyclic Compounds p. 1152 - 1157 (1986)
Update date:2022-08-03
Topics:
Anfinogenov, V. A.
Napilkova, O. A.
Sirotkina, E. E.
Filimonov, V. D.
Khlebnikov, A. I.
The addition of phenothiazine to phenylacetylene in super-base media proceeds regio- and stereoselectively and leads to the predominant formation of cis-10-(2-phenylvinyl)phenothiazine, which is completely converted to its trans-isomer at 200 deg C.Kinetic analysis of the acid hydrolysis of the cis- and trans- isomers has alloved us to assign to it an ACE2 reaction mechanism, similar to the mechanism of hydrolysis of vinyl alkyl ethers.
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