Asymmetric synthesis of α-methylene-γ-butyrolactones fused to carbocyclic rings via the Hosomi reaction of chiral allylsilanes

DOI: 10.1016/S0040-4039(00)92635-2

Source and publish data:

Tetrahedron Letters p. 387 - 390 (1991)

Update date:2022-08-04

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Authors:

Nishitani, Kiyoshi

Yamakawa, Koji

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Article abstract of DOI:10.1016/S0040-4039(00)92635-2

Optically active α-methylene-γ-butyrolactones fused to five or six-membered carbocyclic ring were synthesized in 64-92% enantiomeric excess using the intramolecular Hosomi reaction of ω-formylated β-(chiral)alkoxycarbonylallylsilanes.

Full text of DOI:10.1016/S0040-4039(00)92635-2

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