A New Method for Obtaining 1H NMR Structural Information on Nitroxide Spin Labels Through Reduction to Hydroxylamine by Radiolysis of their Methanolic Solutions

DOI: 10.1039/c39910000024

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Journal of the Chemical Society. Chemical communications p. 24 - 25 (1991)

Update date:2022-08-03

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Authors:

Brik, M. E.

Remita, H.

Delcourt, M. O.

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Article abstract of DOI:10.1039/c39910000024

A preliminary description of a convenient method for the reduction of nitroxide spin labels by a radiolysis technique is described; the main advantage of this procedure is the ease with which nitroxides are converted to the corresponding non-paramagnetic hydroxylamines, the 1H NMR spectra of these hydroxylamines gives structural information on the parent spin labels.

Full text of DOI:10.1039/c39910000024

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