Preparation and reactivity of polyfunctional zinc and copper organometallics bearing sulfur functionalities

DOI: 10.1016/S0040-4020(01)88872-4

Source and publish data:

Tetrahedron p. 2025 - 2043 (1992)

Update date:2022-09-26

Topics:

Authors:

Achyutha Rao

Chou, Tso-Sheng

Schipor, Ioana

Knochel, Paul

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Article abstract of DOI:10.1016/S0040-4020(01)88872-4

Iodomethylthiobenzoate 5 and α-chloroalkyl phenyl sulfides 6 were found to insert zinc dust in THF under very mild conditions (10-25°C, 0.5-2 h) leading to zinc α-thioorganometallics. After a transmetallation with CuCN·2 LiCl, the corresponding copper rea

Full text of DOI:10.1016/S0040-4020(01)88872-4

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