A Chiral Building Block with Bicyclooctanone Skeleton by the Reduction with Baker's Yeast

DOI: 10.1016/S0957-4166(00)80443-7

Source and publish data:

Tetrahedron Asymmetry p. 775 - 782 (1990)

Update date:2022-07-29

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Authors:

Kitahara, Takeshi

Miyake, Masahiro

Kido, Masaru

Mori, Kenji

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Article abstract of DOI:10.1016/S0957-4166(00)80443-7

Preparation of functionalized bicyclo<2.2.2>octan-2-one with high optical purity is described.Reduction of a bridged diketone 2 with baker's yeast gave an endo-hydroxyketone (+)-12 of 98.5-99.5percent e.e. in 91percent yield.X-ray crystallography of its (

Full text of DOI:10.1016/S0957-4166(00)80443-7

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