A Chiral Building Block with Bicyclooctanone Skeleton by the Reduction with Baker's Yeast

DOI: 10.1016/S0957-4166(00)80443-7

Source and publish data:

Tetrahedron Asymmetry p. 775 - 782 (1990)

Update date:2022-07-29

Topics:

Authors:

Kitahara, Takeshi

Miyake, Masahiro

Kido, Masaru

Mori, Kenji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(00)80443-7

Preparation of functionalized bicyclo<2.2.2>octan-2-one with high optical purity is described.Reduction of a bridged diketone 2 with baker's yeast gave an endo-hydroxyketone (+)-12 of 98.5-99.5percent e.e. in 91percent yield.X-ray crystallography of its (

Full text of DOI:10.1016/S0957-4166(00)80443-7

Products guided by the article

Product name:ethyl 4-allyl-2-oxocyclohexaneacetate

Cas No:133382-15-7

R&D Labs maybe for 133382-15-7

Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
Jinhua Haoyuan Chemical CO., LTD(expird)

Contact:86-579-82465583

Address:Jinhua,Zhejiang
Shanghai Topchem Co., LTD

website:http://www.shtopchem.com/

Contact:0086-0576-87776998

Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36

Relevant to this article

Domino reaction to functionalized 2-hydroxybenzophenones from electron-deficient chromones and 1,3-dicarbonyl compounds

Doi:10.1021/jo201384f
(2011)
CoFe2O4/Cu(OH)2 magnetic nanocomposite: An efficient and reusable heterogeneous catalyst for one-pot synthesis of β-hydroxy-1,4-disubstituted-1,2,3-triazoles from epoxides

Doi:10.1039/c9ra06038c
(2019)
L -amino acid amides via dynamic kinetic resolution

Doi:10.1002/adsc.201100389
(2011)
sym-TRIAZINE DERIVATIVES. 9. REACTION OF sym-TRIAZINES CONTAINING TRICHLOROMETHYL AND ETHOXYCARBONYL GROUPS WITH PHENYLHYDRAZINE

Doi:10.1007/BF00473967
(1990)
Physical optical properties and crystal structures of organic 5-sulfosalicylates - Theoretical and experimental study

Doi:10.1016/j.molstruc.2011.06.043
(2011)
Generation of trans-dioxoruthenium(VI) porphyrins: A photochemical approach

Doi:10.1016/j.ica.2011.06.002
(2011)

Article Doi