Rhodium(II)-Catalyzed Cyclization Reactions of Alkynyl-Substituted α-Diazo Ketones

DOI: 10.1021/jo00007a047

Source and publish data:

Journal of Organic Chemistry p. 2523 - 2530 (1991)

Update date:2022-09-26

Topics:

Authors:

Padwa, Albert

Krumpe, Keith E.

Gareau, Yves

Chiacchio, Ugo

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Article abstract of DOI:10.1021/jo00007a047

Treatment of several o-alkynyl-substituted α-diazoacetophenone derivatives with rhodium(II) carboxylates results in the formation of substituted indenones.The simplest mechanism accounting for the results involves addition of a rhodium-stabilized carbenoi

Full text of DOI:10.1021/jo00007a047

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