Rhodium(II)-Catalyzed Cyclization Reactions of Alkynyl-Substituted α-Diazo Ketones

DOI: 10.1021/jo00007a047

Source and publish data:

Journal of Organic Chemistry p. 2523 - 2530 (1991)

Update date:2022-09-26

Topics:

Authors:

Padwa, Albert

Krumpe, Keith E.

Gareau, Yves

Chiacchio, Ugo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00007a047

Treatment of several o-alkynyl-substituted α-diazoacetophenone derivatives with rhodium(II) carboxylates results in the formation of substituted indenones.The simplest mechanism accounting for the results involves addition of a rhodium-stabilized carbenoi

Full text of DOI:10.1021/jo00007a047

Products guided by the article

Product name:decahydro-1,3-dioxo-4-(1-oxo-1H-inden-3-yl)-8-methyl-4,8-epoxycycloheptapyrrole

Cas No:133574-66-0

R&D Labs maybe for 133574-66-0

Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Disynthesis Chemical Technology Co. Ltd.

Contact:+86-571-88194596

Address:Dengyun road 380, Gongshu district, Hangzhou city, China
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town
Shandong Zhongcheng Barium Salt Co., Ltd

Contact:+86-15725732638

Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China

Relevant to this article

Binding of Dihydroxybenzenes in a Synthetic Molecular Clip. Effect of Hydrogen Bonding and ?-Stacking

Doi:10.1021/jo00010a001
(1991)
Synthesis of sterically crowded polyarylated boron-dipyrromethenes

Doi:10.1021/jo2010022
(2011)
A marked synergistic effect in antitumor activity of salan titanium(IV) complexes bearing two differently substituted aromatic rings

Doi:10.1021/ja208219f
(2011)
Organocatalytic synthesis of α-quaternary amino acid derivatives via aza-Friedel-Crafts alkylation of indoles with simple α-amidoacrylates

Doi:10.1016/j.tet.2011.08.039
(2011)
Substituent-dependent, iron-mediated tandem cyclization of diynes with benzaldehyde acetals to form highly functionalized indene derivatives

Doi:10.1002/chem.201101667
(2011)
Rational Design and Optimization of a Novel Class of Macrocyclic Apoptosis Signal-Regulating Kinase 1 Inhibitors

Doi:10.1021/acs.jmedchem.9b01206
(2019)

Article Doi