Bulletin of the Chemical Society of Japan p. 416 - 422 (1991)
Update date:2022-08-04
Topics:
Yoshida, Masato
Sasage, Shuichi
Kawamura, Kyoko
Suzuki, Takashi
Kamigata, Nobumasa
Diphenyl diselenide was found to be readily converted into benzeneselenenyl-m-nitrobenzenesulfonate (PhSeOSO2C6H4NO2-m) by treating with m-nitrobenzenesulfonyl peroxide.When the selenenyl sulfonate thus formed was allowed to react in situ with olefins, such as cyclohexene, 1-octene, or styrene, in the presence of various nucleophiles, the adducts of benzeneselenenyl group and a nucleophile were obtained.As the nucleophiles water, methanol, acetic acid, phenol, and anisole could be employed; oxyselenenylated
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