Methyl Effects in the Cyclization of γ-Epoxy Bis-Sulfones

DOI: 10.1021/jo00011a017

Source and publish data:

Journal of Organic Chemistry p. 3530 - 3537 (1991)

Update date:2022-07-30

Topics: Yield Cyclization Methyl Reaction condition

Authors:

Benedetti, Fabio

Berti, Federico

Fabrissin, Silvio

Gianferrara, Teresa

Risaliti, Amerigo

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Article abstract of DOI:10.1021/jo00011a017

A quantitative study on the effects of methyl and gem-dimethyl groups in the intramolecular ring opening of epoxides by bis-sulfonyl carbanions is reported for the formation of cyclopropanes.Reaction rates are increased by methyl groups on the chain conne

Full text of DOI:10.1021/jo00011a017

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