Journal of Organic Chemistry p. 3530 - 3537 (1991)
Update date:2022-07-30
Topics: Yield Cyclization Methyl Reaction condition
Benedetti, Fabio
Berti, Federico
Fabrissin, Silvio
Gianferrara, Teresa
Risaliti, Amerigo
A quantitative study on the effects of methyl and gem-dimethyl groups in the intramolecular ring opening of epoxides by bis-sulfonyl carbanions is reported for the formation of cyclopropanes.Reaction rates are increased by methyl groups on the chain conne
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